elyeh, I use Outlook 2010 and my phone syncs with my Outlook email account. I would assume Outlook Express settings are similar. You will use the same Outlook info as you have on your computer to setup your Outlook email on your phone. I have Road Runner so I enter my user name, password, incoming and outgoing server info. , etc. just as it is on my computer. Once you finish the setup, your emails should download. I have 9 email accounts setup as POP accounts on my phone, and they all sync ok. None are using an exchange server. By the way, I am using the K9 email app. Samsung's stock email app is sort of similar to setup. Hope this helps.