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Kies Air is great. Manage your phone's files over wifi with it. It comes pre installed. Click the app and it will tell you how to connect to your wifi network and all the files on your phone appear in your browser.
I also really like that you can adjust brightness on any screen or app by holding your finger on the notification bar and swipe left or right. It's super handy
You can text back a pre-written message to a missed call with one click. This feature will be built into ICS just like the screenshot feature.
The camera is very nice. It has a Panoramic mode. That feature will also be built into ICS.