How to set a specific SIM on my S5 Duos to a specific phone number in my agenda?

[Sciroccoss]

Is there any way to set a certain SIM to call a certain number in my agenda? Eg. Most people in my agenda have 2 phone numbers with different network providers. I would like to set the first number to dial with SIM1 as default and the second number to dial with SIM2 as default. Is that possible?
I'm on KitKat4.4.2.

Thank you kindly.