Do you use a different wall charger when you plug it in at night?
Could be an issue with the charger...
Here's what happens when you charge for extended periods of time:
The phone charges to full, then stops the current from flowing from the charger to the battery. The phone runs off battery power until it reaches a certain level (~94-97%, depending on the device), then recharges again. It repeats this cycle until the phone is unplugged.
Here's the thing though...the phone will indicate a "full charged" (100%) during this whole process, but usually after a few minutes of being off of the charger, the battery level will correct itself to it's actual charge level. This *could* make it seem like it's dropping rapidly (if it goes from 100 to 96% in a matter of minutes), when in fact that is perfectly normal, and will level off and start discharging at a normal rate after that.
What it sounds like yours is doing, however, is never restarting that cycle after it reaches full charge the first time. Still though, to drop from 100 to almost nothing just overnight with the phone idle isn't normal either, so there's definitely something else going on.
First thing I'd check is the charger itself...then possibly move on to the battery after that. Try using a different charger (preferably one with the same power output as the original one that comes with the Thunderbolt), and see if the problem persists.