Ok, in bullet form, to keep it simple.
-Samsung uses the USB PD spec, however they implemented the programmable power supply (PPS) mode for the phones and chargers.
-PPS is part of the spec, but has been rarely used until now, meaning most chargers you can find on Amazon/wherever do not support it.
-PPS allows for more/variable voltage and amperage instead of the standard fixed profiles. This is done so voltage can be increased and amperage lowered at the beginning of the charging cycle, which lowers heat output
-The Note 10+ supports up to 45W charging on a PPS charger, the Note 10 only supports 25W.
-Both phones will charge at up to 15W when using a USB PD charger that does not support PPS. doesn't matter the rating of the charger. It can be a 60W charger but will only charge the Note 10's at 15W if it does not support PPS.
-both phones will charge at 25W on the stock charger in the box
- with any USB PD PPS charger, including Samsung's, the Note 10+ will charge at up to 45W, the Note 10 will charge up to 25W, that is the maximum for that phone.
-in terms of raw charging, the 45W charger does not give significant speed increases over the 25W charger because the phone only charges at 45W for the first 30% or so, after 30% it reverts back down to 25W. This is done to keep heat down.
-This means that unless your phone is under about 30% battery, you will not see any improvement at all on the 45W charger compared to the 25W charger.
Personally, I would not buy the Samsung 45W charger if your only intended purpose is to charge your phone with it. If you also have a bunch of USB-C devices that can charge at higher wattages, it might be worth it. i.e. I have an XPS 13 laptop that charges at 45W, the Samsung charger would charge that laptop at 45W just fine. so in a scenario where you have multiple devices that could take advantage of the faster charging speed, and it allows you to only carry one charger that can charge those devices at maximum speed, it might be worth the cost to you. If you're buying it just for the phone, it is not worth it.