Samsung Galaxy S4 Korean (copy), Android Jelly
Bean 4.4.4, GSM, WCDMA, LTE all options are
available when I enter *#*#4636#*#*, but when I try to switch to WCDMA it automatically reverses to GSM only,please help!!
Welcome to Android Central! If it's a knockoff/clone, then all bets are off. The hardware or firmware might be defective, and since it's not a true Samsung phone, you probably won't be able to troubleshoot it like a Samsung phone, or try to re-flash the firmware.
If you go to Settings>Wireless & Networks>More>Cellular/Mobile Networks, can you select the preferred network mode there?
I'm just speculating here, but I wonder if maybe your clone actually doesn't have a CDMA radio, but is running a firmware for a phone that has both CDMA/GSM.