I got my new Google pixel XL 128gb and I tried many times to press the two buttons simultaneously but it will not take a screen shot.
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Yes, this is helpful, but be warned that it won't catch any screen overlays (like Facebook Messengers chat heads), which are closed when GA starts to take the shot (unlike the double-button method).
You can also press and hold the assistant button (the round button between the square and triangle). You can then share it it save to to your Drive account.