- Feb 6, 2011
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This was posted in the comments section of Jerry's most recent "Android and Chill" article. I don't know enough about enough to know if this is accurate and possibly the cause for the Note7's battery issues. I'm hoping one or more of you knows. Thanks.
Joe J1
Interesting thread on reddit :
–]elephantbutt69 673 points 3 days ago*
I inspected the kernel source code. Samsung charges the note 7 battery at just over 4.35v
Older models have 4.35v batteries but only charge to 4.3v.
If you put a generic 4.2v lithium ion battery in, they survive 4.3v with a reduction in charge cycles but anything above that causes formation of metallic lithium dendrites, a non reversible process that eventually causes a fire. This policy makes sense if you have removable batteries as there are lots of fake genuine samsung batteries. But you want maximum battery life using special 4.35v cells. Perhaps they thought with a sealed battery they could hit 4.35v?
The chemistry is not hugely different, just uses more expensive elements. So a factory trying to minimise cost could easily introduce a defect from changing from one type to another etc.
So this tiny change could cause a defective battery to catch fire where it normally would not.
Doesnt matter how you charge it, more how long it sits above 4.30v at ~60-100% float charge.
So samsungs 60% charge resolves 2 issues, peak voltage above 4.3 and energy release on failure.
Imho they need to go back to 4.3v policy rather than just replace and assume its a once off.Lithium batteries used in phones dont catch fire without physical damage like a knife or overvoltage. That's why this is so unusual.
Ps kernel source is available from samsungs website because android is based on linux.
Tldr: policy change from 4.3v float charge to 4.35vwhich I have confirmed by examining source code available on samsungs website would explain the fires
Joe J1
Interesting thread on reddit :
–]elephantbutt69 673 points 3 days ago*
I inspected the kernel source code. Samsung charges the note 7 battery at just over 4.35v
Older models have 4.35v batteries but only charge to 4.3v.
If you put a generic 4.2v lithium ion battery in, they survive 4.3v with a reduction in charge cycles but anything above that causes formation of metallic lithium dendrites, a non reversible process that eventually causes a fire. This policy makes sense if you have removable batteries as there are lots of fake genuine samsung batteries. But you want maximum battery life using special 4.35v cells. Perhaps they thought with a sealed battery they could hit 4.35v?
The chemistry is not hugely different, just uses more expensive elements. So a factory trying to minimise cost could easily introduce a defect from changing from one type to another etc.
So this tiny change could cause a defective battery to catch fire where it normally would not.
Doesnt matter how you charge it, more how long it sits above 4.30v at ~60-100% float charge.
So samsungs 60% charge resolves 2 issues, peak voltage above 4.3 and energy release on failure.
Imho they need to go back to 4.3v policy rather than just replace and assume its a once off.Lithium batteries used in phones dont catch fire without physical damage like a knife or overvoltage. That's why this is so unusual.
Ps kernel source is available from samsungs website because android is based on linux.
Tldr: policy change from 4.3v float charge to 4.35vwhich I have confirmed by examining source code available on samsungs website would explain the fires