The background screen dimms when you pull down the notification bar or quick toggles by design.
However, sometimes if you are in a dark environment and looking at a white screen, the light sensor will pick up light from the screen slightly to cause it to increase the brightess of the screen. Once you pull the quick toggles menu / or notification panel, this causes the web page you are viewing to dimm by design, thus possibly redusing the overall screen brightness as the sensor is picking up less 'screen light' if you will.
I've notice this when switching between apps with bright white screes to darker ones.