In this case, yeah... But I also forgot to mention that your device should support fast charging. Same thing with the cable, if the device can't 'sink' more than a certain amount of current, it doesn't matter that you're using a 5A charger, the phone just won't be able to draw that much. Now, I'm not sure about the Note 3, but I think (again, not sure) it's rated at 2.5A, so a 2.4 should work as expected, but remember that the supplied charger is already 2A, so if it takes 4 hours to charge in that one, the difference won't be abysmal on a 2.4A charger.
And also, make sure your car's outlet can stand it! 2.4A is A LOT to draw from a car and some models won't stand that much current draw (some even have two outlets; one for high-power consumption like DC/AC converters and laptop adapters and one for low-power stuff like the cigarette lighter and such).