It's not too hard. A lot easier than the 2 piece cheap plastic case I had on my S5. I usually started at the headphone jack or charging port as it's easier to get it apart there. The phone actually almost snaps into the front cover, but very easy to remove.
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Oh. Ballistic isn't that difficult to take off as well. Seems easiest to start with the top left. Also, it doesn't collect as much dust as I thought it would. I highly recommend it. Black/white case looks nice too.