Okay, this is with 2degrees (another provider that uses the same frequencies/bands as Vodafone), on 4G:
View attachment 364111
^ note the LTE data arrows (that's what I was missing!)
2degrees again, this time with mobile data off and wifi calling activated:
View attachment 364112
Now for my own usual Vodafone SIM:
View attachment 364113
^ the 5G indicator is visible! Oddly when I tried to activate wifi calling it didn't show the icon for it (a la the second image)
Finally, another provider - Spark. I believe they don't use the same 5G frequency as Vodafone and 2degrees, but they do have a 3G/4G/5G network. However as it probably doesn't run on the same bands as this phone, this was all I saw:
View attachment 364114
Based on all the above, it's probably just going to be a case of installing my regular Vodafone SIM and starting to use it as usual, which I'll probably do in the next week.
Bit surprised the Wifi calling icon wasn't visible with my regular SIM but was with 2degrees. Have I found an anomaly of some sort here?